Please use this identifier to cite or link to this item: http://rdu.iquimica.unam.mx/handle/20.500.12214/1220
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dc.rights.licensehttp://creativecommons.org/licenses/by-nc-nd/4.0es_MX
dc.creatorDAVID MORALES MORALES-
dc.date.accessioned2020-02-18T19:20:10Z-
dc.date.available2020-02-18T19:20:10Z-
dc.date.issued2020-
dc.identifier.urihttp://rdu.iquimica.unam.mx/handle/20.500.12214/1220-
dc.description.abstractA new and facile procedure for the synthesis of non-symmetric phosphinito-thiophosphinito PSCOP pincer complexes based on Ni(II) and Pd(II) was developed. The synthesis of the complexes was carried out in a single step, starting from 3,3-dihydroxydiphenyldisulfide. The Ni(II) complexes were tested as catalysts in C-S and C-Se coupling reactions, being the t Bu derivative 3-Ni the one exhibiting the best performance in both transformations. In this case, the sterics of the substrates was studied, showing that higher steric hindrance leads to lower yields. Analogously, the Pd(II) complexes were used as catalyst in Suzuki-Miyaura couplings of para-substituted bromobenzenes and phenyl boronic acid, being the analogous t Bu derivative complex 3-Pd the best catalysts for this process, exhibiting tolerance to a wide range of functional groups.es_MX
dc.language.isoenges_MX
dc.relation.urihttp://www.elsevier.com/locate/icaes_MX
dc.rightsinfo:eu-repo/semantics/closedAccesses_MX
dc.sourceInorganica Chimica Acta (ISSN 0020-1693) 502, 119283es_MX
dc.titleNovel and facile procedure for the synthesis of Ni(II) and Pd(II) PSCOP pincer complexes: evaluation of their catalytic activity on C-S, C-Se and C-C cross coupling reactionses_MX
dc.typeinfo:eu-repo/semantics/articlees_MX
dc.creator.idinfo:eu-repo/dai/mx/orcid/0000-0002-7984-1819es_MX
dc.subject.ctiinfo:eu-repo/classification/cti/2es_MX
dc.subject.keywordsPSCOP pincer compoundses_MX
dc.subject.keywordsNickel complexeses_MX
dc.subject.keywordsPalladium complexeses_MX
dc.subject.keywordsCross-couplinges_MX
dc.subject.keywordsSuzuki-Miyaura reactiones_MX
dc.type.urihttps://doi.org/10.1016/j.ica.2019.119283es_MX
dc.creator.twoSimon Hernandez Ortega-
dc.creator.threeErnesto Rufino Felipe-
dc.creator.fourHugo Valdés-
dc.creator.idtwoinfo:eu-repo/dai/mx/orcid/0000-0002-1034-5673es_MX
dc.creator.idthreeinfo:eu-repo/dai/mx/orcid/0000-0003-1619-6602es_MX
dc.creator.idfourinfo:eu-repo/dai/mx/orcid/0000-0001-8815-0019es_MX
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