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http://rdu.iquimica.unam.mx/handle/20.500.12214/1228| Título: | C[sbnd]S cross-coupling catalyzed by a series of easily accessible, well defined Ni(II) complexes of the type [(NHC)Ni(Cp)(Br)] |
| Autor: | DAVID MORALES_MORALES |
| ID del Autor: | info:eu-repo/dai/mx/orcid/0000-0002-7984-1819 |
| Resumen: | The synthesis, characterization and catalytic evaluation of a series of NHC-Ni(II) complexes1-Ni(-Me),2-Ni(-nBu) and3-Ni(-Bn) bearing a phthalimide fragment and a cyclopentadienyl (Cp) ligand is reported.The complexes were evaluated in CAS couplings of iodobenzene and a range of thiols. The reactions werecarried out using a catalyst loading of 5 mol % in DMF during 0.5–19 h. Being complex2-Nithe oneexhibiting the best activity for these transformations yielding up to 96% of products in 0.5 h |
| Fecha de publicación: | 2020 |
| Licencia: | http://creativecommons.org/licenses/by-nc-nd/4.0 |
| URI: | http://rdu.iquimica.unam.mx/handle/20.500.12214/1228 |
| metadata.dc.type.uri: | https://doi.org/10.1016/j.jcat.2020.01.016 |
| Lenguaje: | eng |
| Aparece en las colecciones: | Artículos |
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